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New fields of science and technology call for new materials with valuable performance characteristics. Long-term resistance to such temperatures can be found only in polymers with chains made up of thermostable fragments. Particularly interesting in this respect are elementorganic polymers with inorganic and organo-inorganic molecular chains. Eleme
The main focus in this monograph is on models of the kinetics of photo-initiated polymerization of mono- and bi-functional monomers up to the high conversion stage, their derivation, analysis and comparison with the experimental data. This monograph can be useful for scientists, engineers, post-graduate training students and students who are interested in problems both of the polymerization kinetics and general chemical kinetics.
This volume deals with chemistry of polyelectrolytes, namely biocide guanidine containing polymers, discussing both synthesis of new guanidine containing monomers of diallyl and acrylic nature and their structure and investigation of their radical (co)polymerization and properties of new (co)polymers.The first parts of the book describe radical pol
The demand for organosilicon elastomers used in the production of thermally resistant rubbers and organosilicon polymers for making non-metal composite materials is increasing from year to year.This monograph presents a discussion on the methods used for synthesizing and studying properties of newly designed organosilicon polymers, namely organosil
This volume focuses on the dynamical behaviour of low-molecular additives in solid polymer matrixes. It covers: types and models of molecular motion in condensed media; dependence of motional frequency on particle structure and size, temperature, volume and stress; and polymer properties and polymeric structures. Extensive analysis of common regularities of rotational and translational dynamics of molecules introduced into polymers are given. The book also includes experimental techniques for molecular mobility evaluation, and features detailed data on rotational dynamics of additives. It should be of interest to specialists in various fields of polymer physical chemistry and materials science.
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Biomedical Materials and Diagnostics Devices provides an up-to-date overview of the fascinating and emerging field of biomedical materials and devices, fabrication, performance, and uses The biomedical materials with the most promising potential combine biocompatibility with the ability to adjust precisely the biological phenomena in a controlled manner. The world market for biomedical and diagnostic devices is expanding rapidly and the pace of academic research resulted in about 50,000 published papers in recent years. It is timely, therefore, to assemble a volume on this important subject. The chapters in the book seek to address progress in successful design strategies for biomedical mate...
Polymer Syntheses, Volume I presents detailed laboratory instructions for the preparation of polymers by different functional group classes. This book provides the laboratory procedures for the preparation of polymers containing phosphorus in various oxidation states. Organized into 15 chapters, this volume begins with an overview of some selected preparative methods for carrying out the major methods of polymerization in the laboratory. This text then examines the synthesis of phosphonitrilic polymers. Other chapters consider the synthesis of peroxide and hydroperoxide free radical initiators. This book discusses as well the principles involved in the preparation of emulsion polymers, which are applicable to the preparation of polymers of a wide variety of vinyl monomers and many copolymerizations. The final chapter deals with the chemistry of organometallic and organometalloid peroxides. This book is a valuable resource for chemists involved in the designing of phosphorus polymers to meet fire retardant requirements of various products.
Natural polymers have always been used in medicine. However, the development of synthetic polymers for use in medicine has occurred only in the last few decades. The successful applications of these synthetic polymers in medicine depend mainly on their physico-chemical and special characteristics such as biological compatibility with tissues, stability, durability and elasticity. This book deals mainly with the kinetic and structural aspects which are essential for the realization of these characteristics. The authors have examined in detail the processes of diffusion, chemical and biological diintegration, changes in various structural levels induced by chemical and biological media, and the problems of simultaneous influence of these media and mechanical strains on polymers used in medicine. Researchers in the field of polymer physics and chemistry, as well as those who are working with applications of polymers in medicine and biology should find this book useful.