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Transition Metal Reagents and Catalysts
Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Memoirs of the Institute of Scientific and Industrial Research, Osaka University
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Memoirs of the Institute of Scientific and Industrial Research, Osaka University
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Progress in Inorganic Chemistry, Volume 55
The cutting edge of scientific reporting . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science...
Organochromium compounds
Organochromium Compounds is a three-chapter text that covers the major developments in the preparation, characterization, and reaction of the five main classes of organochromium compounds. These classes include the chromium p and solvated sodium and lithium poly(organo)chromate(III) and (II) complexes, carbenoid-chromium, solvated s-bonded organochromium(III) and (II), solvated sodium and lithium poly(organo)chromate(III) and (II) complexes, and unsolvated s-bonded tetra(organo)chromium(IV) compounds. This book will be of value to organic chemists and researchers who are interested in organotransition metal chemistry.
Optical and Optoelectronic Polymers
The field of optoelectronic polymers has continuously expanded in the past two decades because of their innovative applications in a variety of technologies in optoelectronic, photonic and energy research. Groups across the world are still looking into the fundamentals, as well as their applications, which remain to be fully understood and envisioned. This is the first book on the topic for researchers who are entering the field, highlighting the remarkable basic science and technological potential of this class of materials. Chapters will focus on the fundamental concepts as well as up-and-coming research into the applications of these polymers. Chapters will look at topics such as pure organic phosphorescence and external stimuli-responsive luminescent materials that are not covered in other books.
Catalytic Reactions
The Organic Chemistry of Palladium, Volume I1: Catalytic Reactions deals with organic transformations resulting from palladium complexes either stoichiometrically or catalytically. One feature of a reaction catalyzed by transition metals is the absence of evidence for the typical reactive intermediates of organic chemistry, carbanions, and carbonium ions. This lack of evidence is due to the metal acting both as a source and a sink of electrons that result in energetically unfavorable ionic intermediaries. The book explains that palladium (II) can induce C-O bond formation. These reactions involve oxidation of the organic substrate and reduces the Pd(II) to metal, and are not catalytic. Indus...
Biotribology of Natural and Artificial Joints
Biotribology of Natural and Artificial Joints: Reducing Wear Through Material Selection and Geometric Design with Actual Lubrication Mode provides a thorough overview of key issues surrounding the tribological behaviors of both natural and artificial joints, covering methods for optimizing the properties of biomaterials, summarizing the lubrication and contact mechanics of natural and artificial joints, and offering solutions to tribological problems in soft biomaterials and surface failures of materials. Sections cover biomechanics and biotribology of natural and artificial joints, articular cartilage and synovial fluids, methods for improving the tribological properties of artificial joint...
Palladium Catalyzed Oxidation of Hydrocarbons
The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. The development of the organometallic/ catalysis area has resulted in no small way from many contributions from researchers investigating palladium systems. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium(II) salts and complexes. Such homogeneous reactions include oxidative and nonoxi...
The Organic Chemistry of Nickel
The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.
